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Advanced Materials Journal Cover Design Service (Li−Mo−FeCl2)

  • Advanced Materials

  • 11 August 2020

  • A Garnet‐Type Solid‐Electrolyte‐Based Molten Lithium−Molybdenum−Iron(II) Chloride Battery with Advanced Reaction Mechanism

  • Jing XuKai LiuYang JinBin SunZili ZhangYi ChenDawei SuGuoxiu WangHui WuYi Cui

  • 1 Research Center of Grid Energy Storage and Battery Application, School of Electrical Engineering, Zhengzhou University, Zhengzhou, 450001 China

    2 State Key Lab of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084 ChinaResearch Center of Grid Energy Storage and Battery Application, School of

    3 Electrical Engineering, Zhengzhou University, Zhengzhou, 450001 China

  • 10.1002/adma.202000960

  • In article number 2000960, Yang Jin, Hui Wu, Yi Cui, and co-workers design a garnet-type Li6.4La3Zr1.4Ta0.6O12 solid-electrolyte-based molten lithium–molybdenum–iron(II) chloride battery. Different from the conventional reaction mechanism of batteries, this battery synchronizes the reversible Fe–Mo alloying–dealloying reactions with the delithiation–lithiation processes, meaning that the porous Mo skeleton derived from the dealloying reaction can suppress the growth of pure Fe particles. This approach is promising for other alkali metal–metal chloride battery systems.

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